Courtesy of CBSJust ahead of the premiere of her new Showtime documentary, Madonna: Rebel Heart Tour, the Material Girl herself took the passenger seat in the latest installment of “Carpool Karaoke” last night on The Late Late Show with James Corden.

Madonna might have sat down but she didn’t sit still while riding around New York City in an SUV with endearingly star-struck James Corden.

The 58-year-old singer was ageless as ever in her black leather jacket, black jeans and fingerless gloves, rocking attitude from the moment Corden pulled into traffic. The two of them struck a pose for “Vogue” and Madonna ended with her leg stretched to the roof of the car. James tried to do the same, playing it for laughs.

As seen on the teaser released Monday, Madonna straight-up twerked in her seat to “B****, I’m Madonna.” She later shocked her host as she talked about the difference between her life on stage and off, saying she doesn’t drink or smoke and that at home, she’s like Julie Andrews.

The pair also sang “Papa Don’t Preach” and “Don’t Cry for Me Argentina,” from the Evita soundtrack, before moving on to the topic of Michael Jackson. Not only did she kiss, Madonna did tell, admitting that she encouraged Jackson a little with some chardonnay before she made her move on him. “It worked wonders,” she said.

James was clearly having the time of his life and Madonna seemed to enjoy herself, especially while performing “Ray of Light” and “Music.”

“That was the only time I haven’t minded being stuck in traffic,” Madonna said at the end.

Madonna: Rebel Heart Tour premieres on Showtime, Friday, December 9 at 9 p.m. ET/PT, and on Showtime on demand December 10.

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